Mongo can be very weird to adjust to if you’re used to “normal” (SQL) databases. One thing that tripped me up a little was discovering that mongo throws a DuplicateKeyException when you try to insert a duplicate into a field that has a unique index but is not a key. If you see that exception and there’s nothing obviously wrong with your _id field (mongo’s version of a primary key), have a look at any fields you have with a unique index.
Bonus tip: if you’re new to mongo I recommend their recorded Thinking In Documents webinar. It’s a pretty quick (1 hour) overview of how documents and querying work in mongo, I wish I’d found it before I spent so long fumbling around figuring mongo out on my own.